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High Pressure Synthesis of Superconducting Silicon Clathrates and Related Compounds

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The Physics and Chemistry of Inorganic Clathrates

Part of the book series: Springer Series in Materials Science ((SSMATERIALS,volume 199))

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Abstract

The high pressure and high temperature (HPHT) synthesis method is useful in developing metal intercalated silicon clathrate compounds. The barium containing binary type I clathrate compound Ba8Si46 can be prepared under HPHT conditions of 3 GPa at 800 °C, and becomes a superconductor with a transition temperature T c of 8.0 K. A variety of clathrate related compounds with covalently bonded nano-cage structures have been prepared using HPHT conditions with most showing superconductivity. An attempt to prepare carbon analogs of silicon clathrate compounds by the HPHT 3D polymerization of C60 is also introduced.

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Authors and Affiliations

  1. Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima, 739-8527, Japan

    Shoji Yamanaka

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  1. Shoji Yamanaka
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Correspondence to Shoji Yamanaka .

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  1. Dept. of Physics, ISA 2019, University of South Florida, Tampa, Florida, USA

    George S. Nolas

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Yamanaka, S. (2014). High Pressure Synthesis of Superconducting Silicon Clathrates and Related Compounds. In: Nolas, G. (eds) The Physics and Chemistry of Inorganic Clathrates. Springer Series in Materials Science, vol 199. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-9127-4_7

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